Please use this identifier to cite or link to this item: http://repo.lib.jfn.ac.lk/ujrr/handle/123456789/6201
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dc.contributor.authorGurunanthanan, V.-
dc.contributor.authorHettiarachchi, D. U.-
dc.contributor.authorPerera, H. C. S.-
dc.contributor.authorGunathilake, S. S.-
dc.contributor.authorDassanayake, B. S.-
dc.date.accessioned2022-09-06T05:45:47Z-
dc.date.available2022-09-06T05:45:47Z-
dc.date.issued2022-
dc.identifier.urihttp://repo.lib.jfn.ac.lk/ujrr/handle/123456789/6201-
dc.description.abstractThe deterioration of water quality and the presence of lead (Pb), one of the most hazardous heavy metals, have put the health of people all over the world in danger. MgO became popular as an adsorbent in removing Pb in wastewater due to its high adsorption capacity. Immobilizing magnetic nanoparticles inside the adsorbent can be used as an effective way to separate them after the adsorption process. In this study, magnetic MgO nanocomposites were synthesized by a precipitation-calcination method. MgO encompassed Fe and Fe3O4 nanoparticles were synthesized considering the strong magnetic properties of Fe and Fe3O4 and the high adsorption capacity of MgO. The X-ray diffraction patterns of synthesized magnetic MgO confirm the presence of MgO and the cubic structure of the metallic phase of Fe and Fe3O4. Particle morphology and particle size were observed for magnetic MgO and Pb adsorbed magnetic MgO by using SEM images. The observed significant improvement in particle size was mainly due to the formation of magnetic Mg(OH)2 and adsorption of Pb(II) when magnetic MgO nanocomposites were introduced to an aqueous solution containing Pb(II). FTIR analysis on magnetic MgO and Pb(II) adsorbed magnetic MgO confirmed the disappearance of the peak 3648 cm−1 and it suggests that MgO might have been covered by PbO initially. The shifted peak at Pb(II) adsorbed magnetic MgO indicates that the adsorption process occurs through the OH groups. Pb(II) concentrations were determined by an atomic absorption spectrometer. The efficiency of Pb(II) adsorption was investigated using the variations in equilibrium adsorption capacity at different initial concentrations and the variations in adsorption capacity over time. Experimental data agrees with the Langmuir isotherm model and the pseudo-second-order model. This suggests a monolayer chemisorption process, and the Langmuir equation provided the adsorption capacity as 1178.6 mg g−1.en_US
dc.language.isoenen_US
dc.publisherUniversity of Jaffnaen_US
dc.subjectAdsorptionen_US
dc.subjectLead (Pb)en_US
dc.subjectMagnetic MgOen_US
dc.subjectWastewateren_US
dc.titleRemoval of 𝐏b (II) ion using magnetically modified 𝐌go nanoparticlesen_US
dc.typeArticleen_US
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